Simple Elementary
By Tee Shern Ren
Given that humanity is at least 6,000 years old (or older, depending on your Scripture-interpretive leanings), it comes as a surprise to learn that up to 600 years ago — more than 90% of our history as an intellectual, self-aware species — mankind knew at most 11 elements.
Over the 15th to 17th century, we discovered three more, and then humanity went chemically berserk and discovered the next few 70-plus naturally occurring ones, going on to make some more of his own. The story of chemistry is a long one, a historic path through many millennia before arriving at the neat Periodic Table at the last page of our SPM Kimia papers.
The story really began when man started playing around with metal. By a kink in their chemistry, gold and silver are both rare and unreactive, hard to find but always found in their elemental form. All man had to do was to dig (in the right spots) and voila! nuggets of shiny yellow and white. (The lustrous glow of gold and other metals has much to do with the peculiar quantum properties of their electronic arrangements: whenever you admire the glitter of jewellery, you're really watching the unceasing dance of the very building blocks of matter.)
Learning to extract metal from ore, however, was a far bigger technological step forward for man. The first copper, the first iron, the first steel — watersheds in man's march towards modernity. It must have seemed like magic to them, how you could burn some drab mineral with black coal and get shining metal, bright and hard. And chemistry was fanned into flame as people looked on the miraculous transformations you could work, all for the cost of a little energy and the memorisation of the right formula. Dissolve this, burn that, add such a powder into that particular mixture — alchemy promised the world and nearly delivered it, too. Sure, nobody really discovered how to turn mercury into gold (which “would” come, much later) but along the way we learned a lot of other things.
For example, in an effort to distil whatever salts there were in urine (which held promise for alchemists, I suppose, being roughly the same colour as gold if the urinater drinks a suitably small volume of water), Hennig Brand obtained a white chemical that glowed in the dark and burned brilliantly. We call it phosphorus, and we call its glow-in-the-dark phosphorescense. It's the red stuff on the tip of the match, but, more importantly, it's the energy currency in your cells:
every little metabolic action that needs energy input normally gets it by breaking a jittery phosphate ion off an ATP molecule.
Alchemy also discovered nitrogen as the boring stuff in the air which doesn't burn (oxygen is the stuff that does, but we didn't know that either until 1774 — a mere 232 years ago), but it had been working with nitrogen long before that as nitric acid, which, although it doesn't burn, is perfectly capable of corroding nearly any metal known to man. And when you do that, you can isolate the gas hydrogen, which burns brilliantly as the Hindenburg eloquently demonstrated, to give plain
old water. How people discovered that water wasn't one of the indivisible elements of the universe (alongside air, fire, and earth) but was itself "molecules" made by combining smaller things is another story.
Of course, when alchemy graduated into chemistry, the rate of discovery increased by leaps and bounds. Chemistry had an affair with physics, and Sir Humphrey Davy's passing of current through a solution uncovered potassium and sodium. The success of industrial electrolysis also turned aluminium from a semi-precious metal (one ounce of which once cost twice a common worker's daily wages) to something we can afford to throw in the bin. The more energy we put into separating elements, the less able the atoms are able to hold on to their partners in the compounds, and the more of them we are able to isolate — which is partly why the 19th and 20th centuries were a feast of elemental discoveries. We began to master energy, poured it into chemicals, and simply had to see if anything new turned up. (The scientific process here has, of course, been simplified greatly.)
I shouldn't neglect the non-metals: silicon was mistakenly labelled a compound by that same Sir Humphrey Davy, only identified as an element in its own right by Berzelius later on, and now found everywhere you can find an electronic microchip. Fluorine, a (literally) murderously
reactive gas, took 74 years of good chemistry to pin down as an element, and the man who finally did it — Henri Moissan — got the Nobel Prize for his effort. It would go on to form the better half of uranium hexafluoride, notorius for its use in purifying uranium for nuclear power and nuclear bombs.
But surprisingly (or not, depending on your viewpoint) the hardest elements to pin down were the ones that didn't react at all. Remember nitrogen, the gas that wouldn't burn? In distilling it from the air, Lord Rayleigh (he of Rayleigh scattering, the reason the skies are blue) and William Ramsay realized that the "nitrogen" they were getting wasn't completely pure. Sure enough, there was another gas tagging along, one they named "argon", or Greek for "inactive" (a polite synonym for "lazy"). The names of the other noble gases are pretty interesting too — neon is "new", krypton is "hidden", and xenon is "stranger". Aliens who just wouldn't react (not without a large amount of coaxing) had invaded the rightmost strip of the periodic table.
But the discovery that really takes the cake, for me, is helium, which scientists detected and recognised from all of 150 million kilometers away — by radiation from the surface (technically the chromosphere) of the sun. The brave scientists who looked into its light (very carefully), identified a new spectral line, and boldly called it the signature of a new element, were rewarded with the distinction of detecting an element in space before it was found on earth. And its discovery isn't the only thing that is "out of this world". Cool it enough and it transforms into something so weird scientists can only call "helium II", which can creep along walls like
the eerie liquid metal from Terminator and conducts heat (ironically, for something so cold) faster than anything else in the universe.
And finally man got bored with what nature had to offer him and started making up his own elements. It started with radioactivity and the elucidation of the structure of the nucleus: bombard a big atom with enough nucleons and voila! a new element. The first one to be discovered was neptunium, which came after uranium in the same way that Neptune comes after Uranus. Famous plutonium came next in the same vein, followed by more, to make 19 "trans-uranium" elements named so far, plus another five that have not yet been given proper names. The ones waiting for names have appallingly un-pronounce-able nicknames right now — which should I pass you, a few atoms of "Element 116" or "ununhexium"?
But interestingly there was a naming controversy over some of the other trans-uranium elements, started when the Americans wanted to name Element 106 "seaborgium" — despite the fact that Glenn T. Seaborg (who actually “did” transmute lead into gold by stripping protons and neutrons from the atoms, in a process that costs far more than the gold itself is worth at the end) was still alive and kicking when this was suggested, in 1992. In a compromise worked out in 1997,
Element 106 indeed got its name — as part of a "chemistry hall of fame" of sorts, comprising rutherfordium (104), dubnium (105), seaborgium (106), bohrium (107), and hassium (108). One gets the feeling that had this happened a decade later, some American television company would have made a telephone-voting reality show out of the decision.
So we started out intending to do magic, broke the entire universe down to its unique building blocks in the process, and then finished off realising that magic could indeed be done, but at the cost of energy. In Eliot's famous words, we arrived back at the place where we had begun and knew it for the first time: we discovered that God in His wisdom had chosen to make this tremendous universe out of dust, out of atoms: infinitely humble and small, ever reacting and sharing, each wildly unique yet ultimately (at deeper exploration) made of the same things. If we were to listen to the story behind each box in the Periodic Table, then, we could churn out books upon books — and that's not counting the story of the Periodic Table itself ...
